Noun

Singular redox

Plural uncountable

redox (uncountable)

1. a reversible chemical reaction in which one reaction is an oxidation and the reverse is a reduction

Redox (shorthand for reduction-oxidation reaction) describes all chemical reactions in which atoms have their oxidation number (oxidation state) changed. This can be either a simple redox process such as the oxidation of carbon to yield carbon dioxide or the reduction of carbon by hydrogen to yield methane (CH₄), or it can be a complex process such as the oxidation of sugar in the human body through a series of very complex electron transfer processes.

The term redox comes from the two concepts of reduction and oxidation. It can be explained in simple terms:

• Oxidation describes the loss of electrons or an increase in oxidation state by a molecule, atom or ion.
• Reduction describes the gain of electrons or a decrease in oxidation state by a molecule, atom or ion.

Though sufficient for many purposes, these descriptions are not precisely correct. Oxidation and reduction properly refer to a change in oxidation number — the actual transfer of electrons may never occur. Thus, oxidation is better defined as an increase in oxidation number, and reduction as a decrease in oxidation number. In practice, the transfer of electrons will always cause a change in oxidation number, but there are many reactions that are classed as "redox" even though no electron transfer occurs (such as those involving covalent bonds).

Non-redox reactions, which do not involve changes in formal charge, are known as metathesis reactions.